• 主管:

      天津市地质矿产勘查开发局

    • 主办:

      天津地热勘查开发设计院

    • ISSN

      1001-1412  CN 12-1131/P

    西大别小罗山钼多金属矿区花岗斑岩脉年代学、岩石地球化学、Sr-Nd-Pb同位素特征及其地质意义

    Geochronology, Geochemistry, Sr-Nd-Pb Isotopic Characteristics, and Geological Significance of the Ore-related Granite Porphyry from the Xiaoluoshan Molybdenum Polymetallic Deposit in the Western Dabie Orogenic Belt

    • 摘要: 小罗山钼多金属矿床位于西大别灵山岩体南缘,含矿岩体与花岗斑岩脉空间关系密切,其多赋存在花岗斑岩脉裂隙或破碎带中,矿化围岩蚀变具有明显的绢英岩化-泥化-青磐岩化分带特征。LA-ICP-MS锆石U-Pb定年结果表明,小罗山花岗斑岩脉的成岩年龄为117.66±0.74 Ma,为早白垩世中晚期。岩石地球化学数据显示,岩石具有高硅(72.75 %~78.54 %)、高碱(7.99 %~9.82 %)、准铝质-弱过铝质、高岩石分异指数特征;岩石相对富集轻稀土元素(ΣLREE/ΣHREE为5.94~12.78),Eu负异常明显;富集Rb、Th等大离子亲石元素,亏损Nb、P、Sr、Ti等高场强元素。岩石锶元素初始比值为Isr=0.708 023~0.712 109,钕同位素εNd(t)值变化于−9.6~−8.2之间,TDM2为1 802 Ma~1 664 Ma。岩石地球化学和Sr-Nd-Pb同位素特征表明,该区花岗斑岩脉可能是扬子地块北缘古-中元古代地壳物质部分熔融的产物,同时岩石源区有区域上大别片麻岩部分熔融物质的贡献,其形成的地球动力学背景可能为白垩纪构造拆沉作用之后地壳伸展环境。

       

      Abstract: The Xiaoluoshan molybdenum-polymetallic deposit occurs along the southern boundary of the Lingshan intrusive complex within the western Dabie orogenic belt. Mineralization exhibits intimate spatial association with granitic porphyry dikes, predominantly hosted within fractures and breccia zones of these intrusive bodies. The alteration mineralogy displays well-defined zoning patterns characterized by sericitization-argillization-pyritization assemblages, suggesting exploration potential for porphyry-style mineralization at depth. High-precision LA-ICP-MS zircon U-Pb geochronology yields an emplacement age of 117.66±0.74 Ma for the granitic porphyry dikes, corresponding to the middle to late Early Cretaceous. Comprehensive petrochemical analyses reveal the following characteristics: (1) elevated SiO2 contents (72.75 %~78.54 %) with corresponding high alkali concentrations (7.99 %~9.82 %); (2) metaluminous- to weakly peraluminous compositions; (3) pronounced fractionation indices; (4) light rare earth element enrichment (ΣLREE/ΣHREE=5.94-12.78) accompanied by significant negative Eu anomalies; (5) enrichment of large-ion lithophile elements (Rb, Th) coupled with depletion of high-field-strength elements (Nb, P, Sr, Ti). Isotopic investigations demonstrate initial 87Sr/87Sr ratios ranging from 0.708 023 to 0.712 109 (Isr), εNd(t) values between −9.6 and −8.2, and two-stage depleted mantle model ages (TDM2) of 1 802 Ma~1 664 Ma. Integrated geochemical and isotopic evidence indicates that these granitic porphyry dikes likely originated through partial melting of Meso- to Paleoproterozoic crustal materials at the northern Yangtze Block margin, with significant contributions from regional Dabie gneiss protoliths. Their formation is interpreted to have occurred in a post-orogenic extensional regime following Cretaceous post-orogenic extension.

       

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